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Chemische Verbindung Bromderivate
Picture: Christina Beresowski

Influence of nanoparticle size on plasmon-induced reactions

The research work of Christina Beresowski from the Colloid Chemistry group headed by Prof. Dr. Ilko Bald deals with plasmon-induced reactions caused by the excitation of nanoparticles and the associated generation of so-called "hot electrons". In particular, the size effect of the plasmonic nanoparticles on the reaction kinetics is investigated. For this purpose, the molecules to be studied must adsorb on the surface of the nanoparticles. In the next step, the functionalized nanoparticles are dropped onto a silicon wafer, where they aggregate after subsequent drying. Surface-enhanced Raman spectroscopy (SERS) is used to induce and simultaneously follow the reaction.

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Chemische Verbindung Bromderivate
Picture: Christina Beresowski

Grafische Darstellung von Synthese antimikrobieller Polymere
Picture: Anne-C. Lehnen

Antimicrobial Bottle Brush Copolymers

The development of antibiotic resistance in bacteria is a growing problem in our society, making the development of effective alternatives increasingly important. One possible solution are antimicrobial polymers. The main focus of our research is the synthesis and analysis of antimicrobial bottle brush copolymers. It has been shown that bottle brush copolymers have higher antimicrobial activities and lower toxicity towards red blood cells compared to linear chains, resulting in improved biocompatibility. Antimicrobial copolymers are not only effective against normal bacteria, but can also prevent growing of antibiotic-resistant bacteria. In order to access complex macromolecular architectures even faster and easier, new polymerization techniques based on photoiniferter RAFT polymerization are being developed in our group (Polymer Biomaterials Group of Dr. Matthias Hartlieb).

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Grafische Darstellung von Synthese antimikrobieller Polymere
Picture: Anne-C. Lehnen

Optische Fasern
Picture: Claudia Pacholski

Optical Fiber Sensors

The FöWiTec-funded project of the Functional Materials group of Dr. Claudia Pacholski deals with the fabrication of tailored optical fiber sensors and investigates both their chemical and optical properties. The work focuses on equipping the fiber tips with nanomaterials, such as porous silicon and stimuli-responsive polymers. The porous silicon is generated by electrochemical or metal-assisted etching, and both the pore size and the optical response of the material are freely adjustable. By combining the porous material with polymers, optical fiber sensors can be produced to precisely fit a targeted application.

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Optische Fasern
Picture: Claudia Pacholski

Darstellung der Herstellung des Filtermaterials aus schon benutztem Kaffeepulver und der Filterwirkung
Picture: Inga Block

Modifications of spent coffee used as adsorbent for the filtration of water

Water is becoming a highly valuable resource. Hence, economically viable and efficient methods to produce clean water for the growing world population gain more and more importance. One possible treatment for clean water production is the removal of pollutants via adsorption. Although quite expensive, activated carbon (AC) is commonly used for pollutant adsorption. However, spent coffee (SC) is an abundant and cheap raw material that is daily disposed worldwide in large amounts. It is already known for removal of e.g. heavy metals, dyes or organic acids [1-3].

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Darstellung der Herstellung des Filtermaterials aus schon benutztem Kaffeepulver und der Filterwirkung
Picture: Inga Block

Einkristalle einer Nickel-Komplex-Verbindung (die 3 dunkelblau bis lila Kristalle liegen in einer gelb bis roten Flüssigkeit)
Photo: Dr. Eric Sperlich

Crystallization & X-Ray Structure Analysis

Dr. Eric Sperlichheads the X-ray crystallography service group at the Institute of Chemistry at the University of Potsdam. Together with his team, he undertakes the crystallization of substances, the structural analysis of single crystals using X-ray crystallography and the subsequent evaluation. Together with researchers, he has already published more than 50 new crystal structures.
The support service is available to both internal and external scientists as well as business partners.

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Einkristalle einer Nickel-Komplex-Verbindung (die 3 dunkelblau bis lila Kristalle liegen in einer gelb bis roten Flüssigkeit)
Photo: Dr. Eric Sperlich

3-dimensionales Diagramm, das die Partikelgrößenverteilung nach Durchlaufen des neuartigen Chromatographieverfahren von Dr. Marek Bekir zeigt
Picture: Dr. Marek Bekir

Surface Sensitive Filtration of Microparticles

Under the project management of Dr. Marek Bekir, a new technology for chromatography is being developed that is suitable for particles in the micrometer range. A light-responsible surfactant is used for this process. Depending on the material and surface morphology (roughness, porosity) of the particles, different amounts of surfactant are absorbed.

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3-dimensionales Diagramm, das die Partikelgrößenverteilung nach Durchlaufen des neuartigen Chromatographieverfahren von Dr. Marek Bekir zeigt
Picture: Dr. Marek Bekir

Darstellung der Synthese der beschriebenen Ionogelen
Photo: Alyna Lange

Ionic liquids based materials as electrolytes in fuel cells

Alyna Lange’s research in the group of Prof. Andreas Taubert is mainly based on the synthesis, properties and use of ionic liquids (ILs) and their derivatives for the application as electrolytes. ILs are salts which, like our table salt, consist mostly of ions. In contrast to common salts, ILs have a melting point below 100 °C, some are even liquid at room temperature. Moreover these substances have a negligible vapor pressure, are not flammable and show high thermal and electrochemical stability as well as ionic conductivities. These properties make ILs promising candidates as alternative electrolytes for solar cells, batteries or fuel cells.

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Darstellung der Synthese der beschriebenen Ionogelen
Photo: Alyna Lange

LAMP-based detection of viral RNA on a test stripe (scheme adapted from Milenia Biotec GmbH)
Photo: Prof. Frank Bier

Ultra sensitive and robust POCT approaches for diagnostics

Prof. Dr. Frank Bier’s research group of Molecular Bioanalytics and Bioelectronics focuses on medical diagnostics, especially the development of point-of-care testings (POCT), using different molecular biological and biochemical techniques. Currently, the work focuses on various assay developments for the detection of COVID-19. The main motivation is to design smart and innovative POCT suitable for at-home-testing. One of the research projects investigates the detection of viral RNA to enable an early and reliable diagnosis of infections with SARS-CoV-2 and other pathogens. For a simple and sensitive detection a test strip assay format is combined with the much noticed technique of Loop-Mediated Isothermal Amplification (LAMP) of nucleic acids. For the application oriented research projects, the group collaborates with numerous research institutions as well as companies and industries mainly in Brandenburg-Berlin area.

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LAMP-based detection of viral RNA on a test stripe (scheme adapted from Milenia Biotec GmbH)
Photo: Prof. Frank Bier

schematic representation of the absorbing effect of the substance used and the effect on contaminated water
Photo: Prof. Dr. Andreas Taubert

Sustainable and low cost water treatment materials

Adsorbents based on renewable raw and waste materials, e.g. from the food industry and agroindustry, are produced via a variety of chemical modifications, thermal treatment, and addition of further functional components, such as abundant minerals like clay. The resulting materials act as adsorbents that can be used for the removal of heavy metals, organic pollutants, pharmaceuticals, pesticides, herbicides, and biological contamination.

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schematic representation of the absorbing effect of the substance used and the effect on contaminated water
Photo: Prof. Dr. Andreas Taubert

Gold-Nano star
Photo: Prof. Dr. Joachim Koetz

Superstructures with nanoparticles of defined shape and size

The research group of Prof. Joachim Koetz is dealing with the synthesis of nanoparticles of different shape and size and their application as sensor materials and for the surface- enhanced Raman spectroscopy for the detection of molecules and reaction mechanisms. The important thing here is the separation and isolation of anisotropic nanoparticles (nanotriangles and nanostars) and their surface modification. In addition to the self- organization of gold and magnetite nanoparticles, the research is focused on the insertion of these particles into Janus emulsions. This makes it possible to adjust the droplet size of stimuli-sensitive Janus emulsions, and respectively the pore sizes of the resulting aerogels. The ultralight magnetic aerogels can be used for purifying liquids (dye and oil layer separation).

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Gold-Nano star
Photo: Prof. Dr. Joachim Koetz

Destruction of the outer membrane of a microorganism by a polymer
Photo: Dr. Matthias Hartlieb

Polymeric Biomaterials

Antimicrobial resistance (AMR) is one of the most serious issues of today’s public health. This is where the DFG - Emmy Noether research group Polymere Biomaterialien, led by Dr. Matthias Hartlieb, starts searching for possible solutions. The scientists aim to develop membrane active, antimicrobial polymers, which are so selective towards pathogenic bacteria that they compete with conventional antibiotics. Surface coatings (on medical devices or implants) will also be investigated in the future. The advantage of such materials: the development of resistance is almost impossible.

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Destruction of the outer membrane of a microorganism by a polymer
Photo: Dr. Matthias Hartlieb

Schematic representation of the polymerization and material conversion including structural formulas
Photo: Prof. Dr. Helmut Schlaad

Cellulose derived novel bioplastic

This bioplastic is the first polymerization of levoglucosenyl methyl ether (LME), derived from sustainable feedstock (cellulose), and developed in the research group of Prof. Helmut Schlaad.

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Schematic representation of the polymerization and material conversion including structural formulas
Photo: Prof. Dr. Helmut Schlaad